From absorption data, PDMPO exhibited a pKa of 4.20 for (PDMPOH22+ to PDMPOH+). Fluorescence emission measurements revealed large shifts in excited state pKa values with different behaviour when bound to silica ( pKa of 10.4). There is size dependent shift in pKa.
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The DAS28 P index did not significantly change in the patients whose disease remained active. Less improvement in pain was predicted by female sex (ORadj 3.41 steroids steroids, 95% confidence interval [95% CI] 1.35 “8.64) and a high DAS28 P index at baseline (ORadj for tertiles 2.09, 95% CI 1.24 “3.55). Other conventional RA risk factors did not predict pain changes.Conclusion: The factors most likely to predict less improvement in pain in early RA are female sex and a high DAS28 P index.
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